Investigation into the effect of post-annealing on inverted polymer solar cells
Identifieur interne : 000085 ( Main/Repository ); précédent : 000084; suivant : 000086Investigation into the effect of post-annealing on inverted polymer solar cells
Auteurs : RBID : Pascal:14-0027446Descripteurs français
- Pascal (Inist)
- Recuit thermique, Traitement thermique, Cellule solaire organique, Travail sortie, Couche ITO, Addition étain, Couche interfaciale, Dipôle, Combinaison diversité, Anode, Optimisation, Tension circuit ouvert, Facteur remplissage, Conversion énergie, Taux conversion, Haute performance, Polyélectrolyte, Solution aqueuse, Oxyde d'indium, Thiophène dérivé polymère, Ester, Acide butyrique, Composé du fullerène, Argent, Styrènesulfonate polymère, Mélange polymère, Composé conjugué, Fluorène dérivé polymère, ITO.
- Wicri :
- concept : Argent.
English descriptors
- KwdEn :
- Anode, Aqueous solution, Butyric acid, Conjugated compound, Conversion rate, Dipole, Diversity combining, Energy conversion, Ester, Fill factor, Fluorene derivative polymer, Fullerene compounds, Heat treatment, High performance, ITO layers, Indium oxide, Interfacial layer, Open circuit voltage, Optimization, Organic solar cells, Polyelectrolyte, Polymer blends, Silver, Styrenesulfonate polymer, Thermal annealing, Thiophene derivative polymer, Tin addition, Work function.
Abstract
The work-function of indium tin oxide (ITO) electrodes was tuned with an interfacial dipole layer (WPF-oxy-F) to reverse the polarity in polymer solar cells (PSCs) with an inverted structure. The photoactive layer was based on poly(3-hexylthiophene) (P3HT) and [6,6)-phenyl-C61-butyric acid methyl ester (PCBM). Silver (Ag) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) were used as the top anode. The optimized conditions for the fabricated I-PSCs included an open-circuit voltage (Voc) of 0.68 V, a fill factor (FF) of 64%, and a power conversion efficiency (PCE) of 3.86% through post-annealing at 170 C. The high performance of 1-PSC is due partly to the improved interfacial contact at active/PEDOT:PSS and mainly to the increase of the work-function of annealed PEDOT:PSS/Ag at 170 C for 30 min. Here, we investigated the effect of post-annealing on I-PSC devices by carrying out various annealing sequences.
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Pascal:14-0027446Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Investigation into the effect of post-annealing on inverted polymer solar cells</title><author><name>RIRA KANG</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>School of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Cwangju 500-712</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Buk-Gu, Cwangju 500-712</wicri:noRegion></affiliation></author><author><name sortKey="Oh, Seung Hwan" uniqKey="Oh S">Seung-Hwan Oh</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute (KAERI), 29 Geumgu-gil</s1><s2>Jeongup-si, Jeollabuk-do 580-185</s2><s3>KOR</s3><sZ>2 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Jeongup-si, Jeollabuk-do 580-185</wicri:noRegion></affiliation></author><author><name sortKey="Na, Seok In" uniqKey="Na S">Seok-In Na</name><affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Graduate School of Flexible and Printable Electronics, Chonbuk National University, 664-14 Deokjin-dong</s1><s2>Jeonju-si, Jeollabuk-do, 561-756</s2><s3>KOR</s3><sZ>3 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Jeonju-si, Jeollabuk-do, 561-756</wicri:noRegion></affiliation></author><author><name sortKey="Kim, Tae Soo" uniqKey="Kim T">Tae-Soo Kim</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>School of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Cwangju 500-712</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Buk-Gu, Cwangju 500-712</wicri:noRegion></affiliation></author><author><name sortKey="Kim, Dong Yu" uniqKey="Kim D">Dong-Yu Kim</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>School of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Cwangju 500-712</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Buk-Gu, Cwangju 500-712</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Nanobio-Materials and Electronics, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Gwangju 500-712</s2><s3>KOR</s3><sZ>5 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Buk-Gu, Gwangju 500-712</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">14-0027446</idno><date when="2014">2014</date><idno type="stanalyst">PASCAL 14-0027446 INIST</idno><idno type="RBID">Pascal:14-0027446</idno><idno type="wicri:Area/Main/Corpus">000257</idno><idno type="wicri:Area/Main/Repository">000085</idno></publicationStmt><seriesStmt><idno type="ISSN">0927-0248</idno><title level="j" type="abbreviated">Sol. energy mater. sol. cells</title><title level="j" type="main">Solar energy materials and solar cells</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Anode</term><term>Aqueous solution</term><term>Butyric acid</term><term>Conjugated compound</term><term>Conversion rate</term><term>Dipole</term><term>Diversity combining</term><term>Energy conversion</term><term>Ester</term><term>Fill factor</term><term>Fluorene derivative polymer</term><term>Fullerene compounds</term><term>Heat treatment</term><term>High performance</term><term>ITO layers</term><term>Indium oxide</term><term>Interfacial layer</term><term>Open circuit voltage</term><term>Optimization</term><term>Organic solar cells</term><term>Polyelectrolyte</term><term>Polymer blends</term><term>Silver</term><term>Styrenesulfonate polymer</term><term>Thermal annealing</term><term>Thiophene derivative polymer</term><term>Tin addition</term><term>Work function</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Recuit thermique</term><term>Traitement thermique</term><term>Cellule solaire organique</term><term>Travail sortie</term><term>Couche ITO</term><term>Addition étain</term><term>Couche interfaciale</term><term>Dipôle</term><term>Combinaison diversité</term><term>Anode</term><term>Optimisation</term><term>Tension circuit ouvert</term><term>Facteur remplissage</term><term>Conversion énergie</term><term>Taux conversion</term><term>Haute performance</term><term>Polyélectrolyte</term><term>Solution aqueuse</term><term>Oxyde d'indium</term><term>Thiophène dérivé polymère</term><term>Ester</term><term>Acide butyrique</term><term>Composé du fullerène</term><term>Argent</term><term>Styrènesulfonate polymère</term><term>Mélange polymère</term><term>Composé conjugué</term><term>Fluorène dérivé polymère</term><term>ITO</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Argent</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The work-function of indium tin oxide (ITO) electrodes was tuned with an interfacial dipole layer (WPF-oxy-F) to reverse the polarity in polymer solar cells (PSCs) with an inverted structure. The photoactive layer was based on poly(3-hexylthiophene) (P3HT) and [6,6)-phenyl-C61-butyric acid methyl ester (PCBM). Silver (Ag) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) were used as the top anode. The optimized conditions for the fabricated I-PSCs included an open-circuit voltage (V<sub>oc</sub>) of 0.68 V, a fill factor (FF) of 64%, and a power conversion efficiency (PCE) of 3.86% through post-annealing at 170 C. The high performance of 1-PSC is due partly to the improved interfacial contact at active/PEDOT:PSS and mainly to the increase of the work-function of annealed PEDOT:PSS/Ag at 170 C for 30 min. Here, we investigated the effect of post-annealing on I-PSC devices by carrying out various annealing sequences.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0927-0248</s0></fA01><fA03 i2="1"><s0>Sol. energy mater. sol. cells</s0></fA03><fA05><s2>120</s2></fA05><fA06><s3>p. a</s3></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Investigation into the effect of post-annealing on inverted polymer solar cells</s1></fA08><fA11 i1="01" i2="1"><s1>RIRA KANG</s1></fA11><fA11 i1="02" i2="1"><s1>OH (Seung-Hwan)</s1></fA11><fA11 i1="03" i2="1"><s1>NA (Seok-In)</s1></fA11><fA11 i1="04" i2="1"><s1>KIM (Tae-Soo)</s1></fA11><fA11 i1="05" i2="1"><s1>KIM (Dong-Yu)</s1></fA11><fA14 i1="01"><s1>School of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Cwangju 500-712</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Nanobio-Materials and Electronics, Gwangju Institute of Science and Technology, 1 Oryong-Dong</s1><s2>Buk-Gu, Gwangju 500-712</s2><s3>KOR</s3><sZ>5 aut.</sZ></fA14><fA14 i1="03"><s1>Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute (KAERI), 29 Geumgu-gil</s1><s2>Jeongup-si, Jeollabuk-do 580-185</s2><s3>KOR</s3><sZ>2 aut.</sZ></fA14><fA14 i1="04"><s1>Graduate School of Flexible and Printable Electronics, Chonbuk National University, 664-14 Deokjin-dong</s1><s2>Jeonju-si, Jeollabuk-do, 561-756</s2><s3>KOR</s3><sZ>3 aut.</sZ></fA14><fA20><s1>131-135</s1></fA20><fA21><s1>2014</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>18016</s2><s5>354000508232370150</s5></fA43><fA44><s0>0000</s0><s1>© 2014 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>38 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>14-0027446</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Solar energy materials and solar cells</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>The work-function of indium tin oxide (ITO) electrodes was tuned with an interfacial dipole layer (WPF-oxy-F) to reverse the polarity in polymer solar cells (PSCs) with an inverted structure. The photoactive layer was based on poly(3-hexylthiophene) (P3HT) and [6,6)-phenyl-C61-butyric acid methyl ester (PCBM). Silver (Ag) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) were used as the top anode. The optimized conditions for the fabricated I-PSCs included an open-circuit voltage (V<sub>oc</sub>) of 0.68 V, a fill factor (FF) of 64%, and a power conversion efficiency (PCE) of 3.86% through post-annealing at 170 C. The high performance of 1-PSC is due partly to the improved interfacial contact at active/PEDOT:PSS and mainly to the increase of the work-function of annealed PEDOT:PSS/Ag at 170 C for 30 min. Here, we investigated the effect of post-annealing on I-PSC devices by carrying out various annealing sequences.</s0></fC01><fC02 i1="01" i2="X"><s0>001D06C02D1</s0></fC02><fC02 i1="02" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Recuit thermique</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Thermal annealing</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Recocido térmico</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Traitement thermique</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Heat treatment</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Tratamiento térmico</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Cellule solaire organique</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Organic solar cells</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Travail sortie</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Work function</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Función de 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polímero</s0><s5>31</s5></fC03><fC03 i1="29" i2="X" l="FRE"><s0>ITO</s0><s4>INC</s4><s5>82</s5></fC03><fN21><s1>027</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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